Quantum
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Defining the Hund Physics Landscape of Two-Orbital Systems
Researchers identify exotic metals in unexpected quantum systems
Electrons are ubiquitous among atoms, subatomic tokens of energy that can independently change how a system behaves—but they also can change each other. An international research collaboration found that collectively measuring electrons revealed unique and unanticipated findings. The researchers published their results on May 17 in Physical Review Letters.
“It is not feasible to obtain the solution just by tracing the behavior of each individual electron,” said paper author Myung Joon Han, professor of physics at KAIST. “Instead, one should describe or track all the entangled electrons at once. This requires a clever way of treating this entanglement.”
Professor Han and the researchers used a recently developed “many-particle” theory to account for the entangled nature of electrons in solids, which approximates how electrons locally interact with one another to predict their global activity.
Through this approach, the researchers examined systems with two orbitals — the space in which electrons can inhabit. They found that the electrons locked into parallel arrangements within atom sites in solids. This phenomenon, known as Hund’s coupling, results in a Hund’s metal. This metallic phase, which can give rise to such properties as superconductivity, was thought only to exist in three-orbital systems.
“Our finding overturns a conventional viewpoint that at least three orbitals are needed for Hund’s metallicity to emerge,” Professor Han said, noting that two-orbital systems have not been a focus of attention for many physicists. “In addition to this finding of a Hund’s metal, we identified various metallic regimes that can naturally occur in generic, correlated electron materials.”
The researchers found four different correlated metals. One stems from the proximity to a Mott insulator, a state of a solid material that should be conductive but actually prevents conduction due to how the electrons interact. The other three metals form as electrons align their magnetic moments — or phases of producing a magnetic field — at various distances from the Mott insulator. Beyond identifying the metal phases, the researchers also suggested classification criteria to define each metal phase in other systems.
“This research will help scientists better characterize and understand the deeper nature of so-called ‘strongly correlated materials,’ in which the standard theory of solids breaks down due to the presence of strong Coulomb interactions between electrons,” Professor Han said, referring to the force with which the electrons attract or repel each other. These interactions are not typically present in solid materials but appear in materials with metallic phases.
The revelation of metals in two-orbital systems and the ability to determine whole system electron behavior could lead to even more discoveries, according to Professor Han.
“This will ultimately enable us to manipulate and control a variety of electron correlation phenomena,” Professor Han said.
Co-authors include Siheon Ryee from KAIST and Sangkook Choi from the Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory in the United States. Korea’s National Research Foundation and the U.S. Department of Energy’s (DOE) Office of Science, Basic Energy Sciences, supported this work.
-PublicationSiheon Ryee, Myung Joon Han, and SangKook Choi, 2021.Hund Physics Landscape of Two-Orbital Systems, Physical Review Letters, DOI: 10.1103/PhysRevLett.126.206401
-ProfileProfessor Myung Joon HanDepartment of PhysicsCollege of Natural ScienceKAIST
2021.06.17 View 10412 -
Extremely Stable Perovskite Nanoparticles Films for Next-Generation Displays
Researchers have reported an extremely stable cross-linked perovskite nanoparticle that maintains a high photoluminescence quantum yield (PLQY) for 1.5 years in air and harsh liquid environments. This stable material’s design strategies, which addressed one of the most critical problems limiting their practical application, provide a breakthrough for the commercialization of perovskite nanoparticles in next-generation displays and bio-related applications.
According to the research team led by Professor Byeong-Soo Bae, their development can survive in severe environments such as water, various polar solvents, and high temperature with high humidity without additional encapsulation. This development is expected to enable perovskite nanoparticles to be applied to high color purity display applications as a practical color converting material. This result was published as the inside front cover article in Advanced Materials.
Perovskites, which consist of organics, metals, and halogen elements, have emerged as key elements in various optoelectronic applications. The power conversion efficiency of photovoltaic cells based on perovskites light absorbers has been rapidly increased. Perovskites are also great promise as a light emitter in display applications because of their low material cost, facile wavelength tunability, high (PLQY), very narrow emission band width, and wider color gamut than inorganic semiconducting nanocrystals and organic emitters. Thanks to these advantages, perovskites have been identified as a key color-converting material for next-generation high color-purity displays. In particular, perovskites are the only luminescence material that meets Rec. 2020 which is a new color standard in display industry.
However, perovskites are very unstable against heat, moisture, and light, which makes them almost impossible to use in practical applications. To solve these problems, many researchers have attempted to physically prevent perovskites from coming into contact with water molecules by passivating the perovskite grain and nanoparticle surfaces with organic ligands or inorganic shell materials, or by fabricating perovskite-polymer nanocomposites. These methods require complex processes and have limited stability in ambient air and water. Furthermore, stable perovskite nanoparticles in the various chemical environments and high temperatures with high humidity have not been reported yet.
The research team in collaboration with Seoul National University develops siloxane-encapsulated perovskite nanoparticle composite films. Here, perovskite nanoparticles are chemically crosslinked with thermally stable siloxane molecules, thereby significantly improving the stability of the perovskite nanoparticles without the need for any additional protecting layer.
Siloxane-encapsulated perovskite nanoparticle composite films exhibited a high PLQY (> 70%) value, which can be maintained over 600 days in water, various chemicals (alcohol, strong acidic and basic solutions), and high temperatures with high humidity (85℃/85%). The research team investigated the mechanisms impacting the chemical crosslinking and water molecule-induced stabilization of perovskite nanoparticles through various photo-physical analysis and density-functional theory calculation.
The research team confirmed that displays based on their siloxane-perovskite nanoparticle composite films exhibited higher PLQY and a wider color gamut than those of Cd-based quantum dots and demonstrated perfect color converting properties on commercial mobile phone screens. Unlike what was commonly believed in the halide perovskite field, the composite films showed excellent bio-compatibility because the siloxane matrix prevents the toxicity of Pb in perovskite nanoparticle.
By using this technology, the instability of perovskite materials, which is the biggest challenge for practical applications, is greatly improved through simple encapsulation method.
“Perovskite nanoparticle is the only photoluminescent material that can meet the next generation display color standard. Nevertheless, there has been reluctant to commercialize it due to its moisture vulnerability. The newly developed siloxane encapsulation technology will trigger more research on perovskite nanoparticles as color conversion materials and will accelerate early commercialization,” Professor Bae said.
This work was supported by the Wearable Platform Materials Technology Center (WMC) of the Engineering Research Center (ERC) Project, and the Leadership Research Program funded by the National Research Foundation of Korea.
-Publication:
Junho Jang, Young-Hoon Kim, Sunjoon Park, Dongsuk Yoo, Hyunjin Cho, Jinhyeong Jang, Han Beom Jeong, Hyunhwan Lee, Jong Min Yuk, Chan Beum Park, Duk Young Jeon, Yong-Hyun Kim, Byeong-Soo Bae, and Tae-Woo Lee. “Extremely Stable Luminescent Crosslinked Perovskite Nanoparticles under Harsh Environments over 1.5 Years” Advanced Materials, 2020, 2005255. https://doi.org/10.1002/adma.202005255.
Link to download the full-text paper:
https://onlinelibrary.wiley.com/doi/10.1002/adma.202005255
-Profile: Prof. Byeong-Soo Bae (Corresponding author)
bsbae@kaist.ac.kr
Lab. of Optical Materials & Coating
Department of Materials Science and Engineering
Korea Advanced Institute of Science and Technology (KAIST)
2020.12.29 View 15004 -
KAIST Joins IBM Q Network to Accelerate Quantum Computing Research and Foster Quantum Industry
KAIST has joined the IBM Q Network, a community of Fortune 500 companies, academic institutions, startups, and research labs working with IBM to advance quantum computing for business and science.
As the IBM Q Network’s first academic partner in Korea, KAIST will use IBM's advanced quantum computing systems to carry out research projects that advance quantum information science and explore early applications. KAIST will also utilize IBM Quantum resources for talent training and education in preparation for building a quantum workforce for the quantum computing era that will bring huge changes to science and business. By joining the network, KAIST will take a leading role in fostering the ecosystem of quantum computing in Korea, which is expected to be a necessary enabler to realize the Fourth Industrial Revolution.
Professor June-Koo Rhee who also serves as Director of the KAIST Information Technology Research Center (ITRC) of Quantum Computing for AI has led the agreement on KAIST’s joining the IBM Q Network. Director Rhee described quantum computing as "a new technology that can calculate mathematical challenges at very high speed and low power” and also as “one that will change the future.”
Director Rhee said, “Korea started investment in quantum computing relatively late, and thus requires to take bold steps with innovative R&D strategies to pave the roadmap for the next technological leap in the field”. With KAIST joining the IBM Q Network, “Korea will be better equipped to establish a quantum industry, an important foundation for securing national competitiveness,” he added.
The KAIST ITRC of Quantum Computing for AI has been using the publicly available IBM Quantum Experience delivered over the IBM Cloud for research, development and training of quantum algorithms such as quantum artificial intelligence, quantum chemical calculation, and quantum computing education.
KAIST will have access to the most advanced IBM Quantum systems to explore practical research and experiments such as diagnosis of diseases based on quantum artificial intelligence, quantum computational chemistry, and quantum machine learning technology. In addition, knowledge exchanges and sharing with overseas universities and companies under the IBM Q Network will help KAIST strengthen the global presence of Korean technology in quantum computing.
About IBM Quantum
IBM Quantum is an industry-first initiative to build quantum systems for business and science applications. For more information about IBM's quantum computing efforts, please visit www.ibm.com/ibmq.
For more information about the IBM Q Network, as well as a full list of all partners, members, and hubs, visit https://www.research.ibm.com/ibm-q/network/
©Thumbnail Image: IBM.
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2020.09.29 View 9747 -
Quantum Classifiers with Tailored Quantum Kernel
Quantum information scientists have introduced a new method for machine learning classifications in quantum computing. The non-linear quantum kernels in a quantum binary classifier provide new insights for improving the accuracy of quantum machine learning, deemed able to outperform the current AI technology.
The research team led by Professor June-Koo Kevin Rhee from the School of Electrical Engineering, proposed a quantum classifier based on quantum state fidelity by using a different initial state and replacing the Hadamard classification with a swap test. Unlike the conventional approach, this method is expected to significantly enhance the classification tasks when the training dataset is small, by exploiting the quantum advantage in finding non-linear features in a large feature space.
Quantum machine learning holds promise as one of the imperative applications for quantum computing. In machine learning, one fundamental problem for a wide range of applications is classification, a task needed for recognizing patterns in labeled training data in order to assign a label to new, previously unseen data; and the kernel method has been an invaluable classification tool for identifying non-linear relationships in complex data.
More recently, the kernel method has been introduced in quantum machine learning with great success. The ability of quantum computers to efficiently access and manipulate data in the quantum feature space can open opportunities for quantum techniques to enhance various existing machine learning methods.
The idea of the classification algorithm with a nonlinear kernel is that given a quantum test state, the protocol calculates the weighted power sum of the fidelities of quantum data in quantum parallel via a swap-test circuit followed by two single-qubit measurements (see Figure 1). This requires only a small number of quantum data operations regardless of the size of data. The novelty of this approach lies in the fact that labeled training data can be densely packed into a quantum state and then compared to the test data.
The KAIST team, in collaboration with researchers from the University of KwaZulu-Natal (UKZN) in South Africa and Data Cybernetics in Germany, has further advanced the rapidly evolving field of quantum machine learning by introducing quantum classifiers with tailored quantum kernels.This study was reported at npj Quantum Information in May.
The input data is either represented by classical data via a quantum feature map or intrinsic quantum data, and the classification is based on the kernel function that measures the closeness of the test data to training data.
Dr. Daniel Park at KAIST, one of the lead authors of this research, said that the quantum kernel can be tailored systematically to an arbitrary power sum, which makes it an excellent candidate for real-world applications.
Professor Rhee said that quantum forking, a technique that was invented by the team previously, makes it possible to start the protocol from scratch, even when all the labeled training data and the test data are independently encoded in separate qubits.
Professor Francesco Petruccione from UKZN explained, “The state fidelity of two quantum states includes the imaginary parts of the probability amplitudes, which enables use of the full quantum feature space.”
To demonstrate the usefulness of the classification protocol, Carsten Blank from Data Cybernetics implemented the classifier and compared classical simulations using the five-qubit IBM quantum computer that is freely available to public users via cloud service. “This is a promising sign that the field is progressing,” Blank noted.
Link to download the full-text paper:
https://www.nature.com/articles/s41534-020-0272-6
-Profile
Professor June-Koo Kevin Rhee
rhee.jk@kaist.ac.kr
Professor, School of Electrical Engineering
Director, ITRC of Quantum Computing for AIKAIST
Daniel Kyungdeock Parkkpark10@kaist.ac.krResearch Assistant ProfessorSchool of Electrical EngineeringKAIST
2020.07.07 View 13422 -
Scientists Observe the Elusive Kondo Screening Cloud
Scientists ended a 50-year quest by directly observing a quantum phenomenon
An international research group of Professor Heung-Sun Sim has ended a 50-year quest by directly observing a quantum phenomenon known as a Kondo screening cloud. This research, published in Nature on March 11, opens a novel way to engineer spin screening and entanglement. According to the research, the cloud can mediate interactions between distant spins confined in quantum dots, which is a necessary protocol for semiconductor spin-based quantum information processing. This spin-spin interaction mediated by the Kondo cloud is unique since both its strength and sign (two spins favor either parallel or anti-parallel configuration) are electrically tunable, while conventional schemes cannot reverse the sign.
This phenomenon, which is important for many physical phenomena such as dilute magnetic impurities and spin glasses, is essentially a cloud that masks magnetic impurities in a material. It was known to exist but its spatial extension had never been observed, creating controversy over whether such an extension actually existed.
Magnetism arises from a property of electrons known as spin, meaning that they have angular momentum aligned in one of either two directions, conventionally known as up and down. However, due to a phenomenon known as the Kondo effect, the spins of conduction electrons—the electrons that flow freely in a material—become entangled with a localized magnetic impurity, and effectively screen it. The strength of this spin coupling, calibrated as a temperature, is known as the Kondo temperature.
The size of the cloud is another important parameter for a material containing multiple magnetic impurities because the spins in the cloud couple with one another and mediate the coupling between magnetic impurities when the clouds overlap. This happens in various materials such as Kondo lattices, spin glasses, and high temperature superconductors.
Although the Kondo effect for a single magnetic impurity is now a text-book subject in many-body physics, detection of its key object, the Kondo cloud and its length, has remained elusive despite many attempts during the past five decades. Experiments using nuclear magnetic resonance or scanning tunneling microscopy, two common methods for understanding the structure of matter, have either shown no signature of the cloud, or demonstrated a signature only at a very short distance, less than 1 nanometer, so much shorter than the predicted cloud size, which was in the micron range.
In the present study, the authors observed a Kondo screening cloud formed by an impurity defined as a localized electron spin in a quantum dot—a type of “artificial atom”—coupled to quasi-one-dimensional conduction electrons, and then used an interferometer to measure changes in the Kondo temperature, allowing them to investigate the presence of a cloud at the interferometer end.
Essentially, they slightly perturbed the conduction electrons at a location away from the quantum dot using an electrostatic gate. The wave of conducting electrons scattered by this perturbation returned back to the quantum dot and interfered with itself. This is similar to how a wave on a water surface being scattered by a wall forms a stripe pattern. The Kondo cloud is a quantum mechanical object which acts to preserve the wave nature of electrons inside the cloud.
Even though there is no direct electrostatic influence of the perturbation on the quantum dot, this interference modifies the Kondo signature measured by electron conductance through the quantum dot if the perturbation is present inside the cloud. In the study, the researchers found that the length as well as the shape of the cloud is universally scaled by the inverse of the Kondo temperature, and that the cloud’s size and shape were in good agreement with theoretical calculations.
Professor Sim at the Department of Physics proposed the method for detecting the Kondo cloud in the co-research with the RIKEN Center for Emergent Matter Science, the City University of Hong Kong, the University of Tokyo, and Ruhr University Bochum in Germany.
Professor Sim said, “The observed spin cloud is a micrometer-size object that has quantum mechanical wave nature and entanglement. This is why the spin cloud has not been observed despite a long search. It is remarkable in a fundamental and technical point of view that such a large quantum object can now be created, controlled, and detected.
Dr. Michihisa Yamamoto of the RIKEN Center for Emergent Matter Science also said, “It is very satisfying to have been able to obtain real space image of the Kondo cloud, as it is a real breakthrough for understanding various systems containing multiple magnetic impurities. The size of the Kondo cloud in semiconductors was found to be much larger than the typical size of semiconductor devices.”
Publication:
Borzenets et al. (2020) Observation of the Kondo screening cloud. Nature, 579. pp.210-213. Available online at https://doi.org/10.1038/s41586-020-2058-6
Profile:
Heung-Sun Sim, PhD
Professor
hssim@kaist.ac.kr
https://qet.kaist.ac.kr/
Quantum Electron Correlation & Transport Theory Group (QECT Lab)
https://qc.kaist.ac.kr/index.php/group1/
Center for Quantum Coherence In COndensed Matter
Department of Physics
https://www.kaist.ac.kr
Korea Advanced Institute of Science and Technology (KAIST)
Daejeon, Republic of Korea
2020.03.13 View 17536 -
Black Phosphorous Tunnel Field-Effect Transistor as an Alternative Ultra-low Power Switch
Researchers have reported a black phosphorus transistor that can be used as an alternative ultra-low power switch. A research team led by Professor Sungjae Cho in the KAIST Department of Physics developed a thickness-controlled black phosphorous tunnel field-effect transistor (TFET) that shows 10-times lower switching power consumption as well as 10,000-times lower standby power consumption than conventional complementary metal-oxide-semiconductor (CMOS) transistors.
The research team said they developed fast and low-power transistors that can replace conventional CMOS transistors. In particular, they solved problems that have degraded TFET operation speed and performance, paving the way to extend Moore’s Law.
In the study featured in Nature Nanotechnology last month, Professor Cho’s team reported a natural heterojunction TFET with spatially varying layer thickness in black phosphorous without interface problems. They achieved record-low average subthreshold swing values over 4-5 dec of current and record-high, on-state current, which allows the TFETs to operate as fast as conventional CMOS transistors with as much lower power consumption.
"We successfully developed the first transistor that achieved the essential criteria for fast, low-power switching. Our newly developed TFETs can replace CMOS transistors by solving a major issue regarding the performance degradation of TFETs,"Professor Cho said.
The continuous down-scaling of transistors has been the key to the successful development of current information technology. However, with Moore’s Law reaching its limits due to the increased power consumption, the development of new alternative transistor designs has emerged as an urgent need.
Reducing both switching and standby power consumption while further scaling transistors requires overcoming the thermionic limit of subthreshold swing, which is defined as the required voltage per ten-fold current increase in the subthreshold region. In order to reduce both the switching and standby power of CMOS circuits, it is critical to reduce the subthreshold swing of the transistors.
However, there is fundamental subthreshold swing limit of 60 mV/dec in CMOS transistors, which originates from thermal carrier injection. The International Roadmap for Devices and Systems has already predicted that new device geometries with new materials beyond CMOS will be required to address transistor scaling challenges in the near future. In particular, TFETs have been suggested as a major alternative to CMOS transistors, since the subthreshold swing in TFETs can be substantially reduced below the thermionic limit of 60 mV/dec. TFETs operate via quantum tunneling, which does not limit subthreshold swing as in thermal injection of CMOS transistors.
In particular, heterojunction TFETs hold significant promise for delivering both low subthreshold swing and high on-state current. High on-current is essential for the fast operation of transistors since charging a device to on state takes a longer time with lower currents. Unlike theoretical expectations, previously developed heterojunction TFETs show 100-100,000x lower on-state current (100-100,000x slower operation speeds) than CMOS transistors due to interface problems in the heterojunction. This low operation speed impedes the replacement of CMOS transistors with low-power TFETs.
Professor Cho said, “We have demonstrated for the first time, to the best of our knowledge, TFET optimization for both fast and ultra-low-power operations, which is essential to replace CMOS transistors for low-power applications.” He said he is very delighted to extend Moore’s Law, which may eventually affect almost every aspect of life and society. This study (https://doi.org/10.1038/s41565-019-0623-7) was supported by the National Research Foundation of Korea.
Publication:
Kim et al. (2020) Thickness-controlled black phosphorus tunnel field-effect transistor for low-power switches. Nature Nanotechnology. Available online at https://doi.org/10.1038/s41565-019-0623-7
Profile:
Professor Sungjae Cho
sungjae.cho@kaist.ac.kr
Department of Physics
http://qtak.kaist.ac.kr/
KAIST
Profile:
Seungho Kim, PhD Candidate
krksh21@kaist.ac.kr
Department of Physics
http://qtak.kaist.ac.kr/
KAIST
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2020.02.21 View 13408 -
Professor Sungyeol Choi Receives Science and ICT Ministerial Commendation
< Professor Sungyeol Choi >
Professor Sungyeol Choi from the Department of Nuclear and Quantum Engineering received the Science and ICT Ministerial Commendation on the 9th Annual Nuclear Safety and Promotion Day last month, in recognition of his contributions to the promotion of nuclear energy through the safe management of spent nuclear fuel and radioactive waste.
Professor Choi developed high-precision, multi-physics codes that can predict and prevent abnormal power fluctuations caused by boron hideout within nuclear fuel in a pressurized water reactor, solving the problem that has caused economic losses of tens of billions of won every year from industrial sites.
He is now developing a new technology that can reduce high-level waste by recycling spent nuclear fuel, while preventing nuclear material from being used for nuclear weapons, which is one of the biggest challenges faced by the nuclear industry.
In 2017, his first year in office as a KAIST professor, Professor Choi was selected as the youngest and the only member under 50 of the Standing Scientific Advisory Committee at the Information Exchange Meeting on Partitioning and Transmutation (IEMPT), an authoritative association on the disposal of high-level nuclear waste.
The following year, he became the first Korean to receive the Early Career Award, which is given to one person every two years by the International Youth Nuclear Congress.
2020.01.15 View 6037 -
Ultrafast Quantum Motion in a Nanoscale Trap Detected
< Professor Heung-Sun Sim (left) and Co-author Dr. Sungguen Ryu (right) >
KAIST researchers have reported the detection of a picosecond electron motion in a silicon transistor. This study has presented a new protocol for measuring ultrafast electronic dynamics in an effective time-resolved fashion of picosecond resolution. The detection was made in collaboration with Nippon Telegraph and Telephone Corp. (NTT) in Japan and National Physical Laboratory (NPL) in the UK and is the first report to the best of our knowledge.
When an electron is captured in a nanoscale trap in solids, its quantum mechanical wave function can exhibit spatial oscillation at sub-terahertz frequencies. Time-resolved detection of such picosecond dynamics of quantum waves is important, as the detection provides a way of understanding the quantum behavior of electrons in nano-electronics. It also applies to quantum information technologies such as the ultrafast quantum-bit operation of quantum computing and high-sensitivity electromagnetic-field sensing. However, detecting picosecond dynamics has been a challenge since the sub-terahertz scale is far beyond the latest bandwidth measurement tools.
A KAIST team led by Professor Heung-Sun Sim developed a theory of ultrafast electron dynamics in a nanoscale trap, and proposed a scheme for detecting the dynamics, which utilizes a quantum-mechanical resonant state formed beside the trap. The coupling between the electron dynamics and the resonant state is switched on and off at a picosecond so that information on the dynamics is read out on the electric current being generated when the coupling is switched on.
NTT realized, together with NPL, the detection scheme and applied it to electron motions in a nanoscale trap formed in a silicon transistor. A single electron was captured in the trap by controlling electrostatic gates, and a resonant state was formed in the potential barrier of the trap.
The switching on and off of the coupling between the electron and the resonant state was achieved by aligning the resonance energy with the energy of the electron within a picosecond. An electric current from the trap through the resonant state to an electrode was measured at only a few Kelvin degrees, unveiling the spatial quantum-coherent oscillation of the electron with 250 GHz frequency inside the trap.
Professor Sim said, “This work suggests a scheme of detecting picosecond electron motions in submicron scales by utilizing quantum resonance. It will be useful in dynamical control of quantum mechanical electron waves for various purposes in nano-electronics, quantum sensing, and quantum information”.
This work was published online at Nature Nanotechnology on November 4. It was partly supported by the Korea National Research Foundation through the SRC Center for Quantum Coherence in Condensed Matter. For more on the NTT news release this article, please visit https://www.ntt.co.jp/news2019/1911e/191105a.html
-ProfileProfessor Heung-Sun Sim
Department of PhysicsDirector, SRC Center for Quantum Coherence in Condensed Matterhttps://qet.kaist.ac.kr KAIST
-Publication:Gento Yamahata, Sungguen Ryu, Nathan Johnson, H.-S. Sim, Akira Fujiwara, and Masaya Kataoka. 2019. Picosecond coherent electron motion in a silicon single-electron source. Nature Nanotechnology (Online Publication). 6 pages. https://doi.org/10.1038/s41565-019-0563-2
2019.11.05 View 19558 -
Two More Cross-generation Collaborative Labs Open
< President Sung-Chul Shin (sixth from the left) and Professor Sun Chang Kim (seventh from the left) at the signboard ceremony of KAIST BioDesigneering Laboratory >
KAIST opened two more cross-generation collaborative labs last month. KAIST BioDesigneering Laboratory headed by Professor Sun Chang Kim from the Department of Biological Sciences and Nanophotonics Laboratory led by Professor Yong-Hee Lee from the Department of Physics have been selected to receive 500 million KRW funding for five years.
A four-member selection committee including the former President of ETH Zürich Professor Emeritus Ralph Eichler and Professor Kwang-Soo Kim of Harvard Medical School conducted a three-month review and evaluation for this selection to be made. With these two new labs onboard, a total of six cross-generation collaborative labs will be operated on campus.
The operation of cross-generation collaborative labs has been in trial since March last year, as one of the KAIST’s Vision 2031 research innovation initiatives. This novel approach is to pair up senior and junior faculty members for sustaining research and academic achievements even after the senior researcher retires, so that the spectrum of knowledge and research competitiveness can be extended to future generations. The selected labs will be funded for five years, and the funding will be extended if necessary. KAIST will continue to select new labs every year.
One of this year’s selectees Professor Sun Chang Kim will be teamed up with Professor Byung-Kwan Cho from the same department and Professor Jung Kyoon Choi from the Department of Bio and Brain Engineering to collaborate in the fields of synthetic biology, systems biology, and genetic engineering. This group mainly aims at designing and synthesizing optimal genomes that can efficiently manufacture protein drug and biomedical active materials. They will also strive to secure large amounts of high-functioning natural active substances, new adhesive antibacterial peptides, and eco-friendly ecological restoration materials. It is expected that collaboration between these three multigenerational professors will help innovate their bio-convergence technology and further strengthen their international competitiveness in the global bio-market.
Another world-renowned scholar Professor Yong-Hee Lee of photonic crystal laser study will be joined by Professor Minkyo Seo from the same department and Professor Hansuek Lee from the Graduate School of Nanoscience and Technology. They will explore the extreme limits of light-material interaction based on optical micro/nano resonators, with the goal of developing future nonlinear optoelectronic and quantum optical devices. The knowledge and technology newly gained from the research are expected to provide an important platform for a diverse range of fields from quantum communications to biophysics.
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2019.09.06 View 11872 -
Synthesizing Single-Crystalline Hexagonal Graphene Quantum Dots
(Figure: Uniformly ordered single-crystalline graphene quantum dots of various sizes synthesized through solution chemistry.)
A KAIST team has designed a novel strategy for synthesizing single-crystalline graphene quantum dots, which emit stable blue light. The research team confirmed that a display made of their synthesized graphene quantum dots successfully emitted blue light with stable electric pressure, reportedly resolving the long-standing challenges of blue light emission in manufactured displays. The study, led by Professor O Ok Park in the Department of Chemical and Biological Engineering, was featured online in Nano Letters on July 5.
Graphene has gained increased attention as a next-generation material for its heat and electrical conductivity as well as its transparency. However, single and multi-layered graphene have characteristics of a conductor so that it is difficult to apply into semiconductor. Only when downsized to the nanoscale, semiconductor’s distinct feature of bandgap will be exhibited to emit the light in the graphene. This illuminating featuring of dot is referred to as a graphene quantum dot.
Conventionally, single-crystalline graphene has been fabricated by chemical vapor deposition (CVD) on copper or nickel thin films, or by peeling graphite physically and chemically. However, graphene made via chemical vapor deposition is mainly used for large-surface transparent electrodes. Meanwhile, graphene made by chemical and physical peeling carries uneven size defects.
The research team explained that their graphene quantum dots exhibited a very stable single-phase reaction when they mixed amine and acetic acid with an aqueous solution of glucose. Then, they synthesized single-crystalline graphene quantum dots from the self-assembly of the reaction intermediate. In the course of fabrication, the team developed a new separation method at a low-temperature precipitation, which led to successfully creating a homogeneous nucleation of graphene quantum dots via a single-phase reaction.
Professor Park and his colleagues have developed solution phase synthesis technology that allows for the creation of the desired crystal size for single nanocrystals down to 100 nano meters. It is reportedly the first synthesis of the homogeneous nucleation of graphene through a single-phase reaction.
Professor Park said, "This solution method will significantly contribute to the grafting of graphene in various fields. The application of this new graphene will expand the scope of its applications such as for flexible displays and varistors.”
This research was a joint project with a team from Korea University under Professor Sang Hyuk Im from the Department of Chemical and Biological Engineering, and was supported by the National Research Foundation of Korea, the Nano-Material Technology Development Program from the Electronics and Telecommunications Research Institute (ETRI), KAIST EEWS, and the BK21+ project from the Korean government.
2019.08.02 View 35197 -
Permanent, Wireless Self-charging System Using NIR Band
(Professor Jung-Yong Lee from the Graduate School of Energy, Environment, Water and Sustainability)
As wearable devices are emerging, there are numerous studies on wireless charging systems. Here, a KAIST research team has developed a permanent, wireless self-charging platform for low-power wearable electronics by converting near-infrared (NIR) band irradiation to electrical energy. This novel technology can be applied to flexible, wearable charging systems without needing any attachments.
Colloidal-quantum-dots (CQDs) are promising materials for manufacturing semiconductors; in particular, PbS-based CQDs have facile optical tunability from the visible to infrared wavelength region. Hence, they can be applied to various devices, such as lighting, photovoltaics (PVs), and photodetectors.
Continuous research on CQD-based optoelectronic devices has increased their power conversion efficiency (PCE) to 12%; however, applicable fields have not yet been found for them. Meanwhile, wearable electronic devices commonly face the problem of inconvenient charging systems because users have to constantly charge batteries attached to an energy source.
A joint team led by Professor Jung-Yong Lee from the Graduate School of Energy, Environment, Water and Sustainability and Jang Wok Choi from Seoul National University decided to apply CQD PVs, which have high quantum efficiency in NIR band to self-charging systems on wearable devices.
They employed a stable and efficient NIR energy conversion strategy. The system was comprised of a PbS CQD-based PV module, a flexible interdigitated lithium-ion battery, and various types of NIR-transparent films.
The team removed the existing battery from the already commercialized wearable healthcare bracelet and replaced it with the proposed self-charging system. They confirmed that the system can be applied to a low power wearable device via the NIR band.
There have been numerous platforms using solar irradiation, but the newly developed platform has more advantages because it allows conventional devices to be much more comfortable to wear and charged easily in everyday life using various irradiation sources for constant charging.
With this aspect, the proposed platform facilitates more flexible designs, which are the important component for actual commercialization. It also secures higher photostability and efficient than existing structures.
Professor Lee said, “By using the NIR band, we proposed a new approach to solve charging system issues of wearable devices. I believe that this platform will be a novel platform for energy conversion and that its application can be further extended to various fields, including mobiles, IoTs, and drones.”
This research, led by PhD Se-Woong Baek and M.S. candidate Jungmin Cho, was published in Advanced Materials on May 11.
Figure 1. a) Conceptual NIR-driven self-charging system including a flexible CQD PVs module and an interdigitatedly structured LIB. b) Photographic images of a conventional wearable healthcare bracelet and a self-charging system-integrated wearable device.
Figure 2. Illustration of the CQD PVs structure and performance of the wireless self-charging platform.
2018.10.08 View 9057 -
Improved Efficiency of CQD Solar Cells Using an Organic Thin Film
(from left: Professor Jung-Yong Lee and Dr. Se-Woong Baek)
Recently, the power conversion efficiency (PCE) of colloidal quantum dot (CQD)-based solar cells has been enhanced, paving the way for their commercialization in various fields; nevertheless, they are still a long way from being commercialized due to their efficiency not matching their stability. In this research, a KAIST team achieved highly stable and efficient CQD-based solar cells by using an amorphous organic layer to block oxygen and water permeation.
CQD-based solar cells are light-weight, flexible, and they boost light harvesting by absorbing near-infrared lights. Especially, they draw special attention for their optical properties controlled efficiently by changing the quantum dot sizes. However, they are still incompatible with existing solar cells in terms of efficiency, stability, and cost. Therefore, there is great demand for a novel technology that can simultaneously improve both PCE and stability while using an inexpensive electrode material.
Responding to this demand, Professor Jung-Yong Lee from the Graduate School of Energy, Environment, Water and Sustainability and his team introduced a technology to improve the efficiency and stability of CQD-based solar cells.
The team found that an amorphous organic thin film has a strong resistance to oxygen and water. Using these properties, they employed this doped organic layer as a top-hole selective layer (HSL) for the PbS CQD solar cells, and confirmed that the hydro/oxo-phobic properties of the layer efficiently protected the PbS layer. According to the molecular dynamics simulations, the layer significantly postponed the oxygen and water permeation into the PbS layer. Moreover, the efficient injection of the holes in the layer reduced interfacial resistance and improved performance.
With this technology, the team finally developed CQD-based solar cells with excellent stability. The PCE of their device stood at 11.7% and maintained over 90% of its initial performance when stored for one year under ambient conditions.
Professor Lee said, “This technology can be also applied to QD LEDs and Perovskite devices. I hope this technology can hasten the commercialization of CQD-based solar cells.”
This research, led by Dr. Se-Woong Baek and a Ph.D. student, Sang-Hoon Lee, was published in Energy & Environmental Science on May 10.
Figure 1. The schematic of the equilibrated structure of the amorphous organic film
Figure 2. Schematic illustration of CQD-based solar cells and graphs showing their performance
2018.08.27 View 8885