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The Real Time Observation of the Birth of a Molecule
From right to left: Dr. Kyung-Hwan Kim, Professor Hyotcherl Lhee, and Jong-Gu Kim, a Ph.D. candidate
Professor Hyotcherl Lhee of the Department of Chemistry at KAIST and Japanese research teams jointly published their research results showing that they have succeeded in the direct observation of how atoms form a molecule in the online issue of Nature on February 19, 2015.
The researchers used water in which gold atoms ([Au(CN) 2- ]) are dissolved and fired X-ray pulses over the specimen in femtosecond timescales to study chemical reactions taking place among the gold atoms. They were able to examine in real time the instant process of how gold atoms bond together to become a molecule, to a trimer or tetramer state.
This direct viewing of the formation of a gold trimer complex ([Au(CN) 2- ] 3 ) will provide an opportunity to understand complex chemical and biological systems.
For details, please see the following press release that was distributed by the High Energy Accelerator Research Organization, KEK, in Japan:
Direct Observation of Bond Formations
February 18, 2015
A collaboration between researchers from KEK, the Institute for Basic Science (IBS), the Korea Advanced Institute of Science and Technology (KAIST), RIKEN, and the Japan Synchrotron Radiation Research Institute (JASRI) used the SACLA X-ray free electron laser (XFEL) facility for a real time visualization of the birth of a molecular that occurs via photoinduced formation of a chemical bonds. This achievement was published in the online version of the scientific journal “Nature” (published on 19 February 2015).
Direct “observation” of the bond making, through a chemical reaction, has been longstanding dream for chemists. However, the distance between atoms is very small, at about 100 picometer, and the bonding is completed very quickly, taking less than one picosecond (ps). Hence, previously, one could only imagine the bond formation between atoms while looking at the chemical reaction progressing in the test-tube.
In this study, the research group focused on the process of photoinduced bond formation between gold (Au) ions dissolved in water. In the ground state (S 0 state in Fig. 1) Au ions that are weakly bound to each other by an electron affinity and aligned in a bent geometry. Upon a photoexcitation, the S 0 state rapidly converts into an excited (S 1 state in Fig. 1) state where Au-Au covalent bonds are formed among Au ions aligned in a linear geometry. Subsequently, the S 1 state transforms to a triplet state (T 1 state in Fig. 1) in 1.6 ps while accompanying further contraction of Au-Au bonds by 0.1 Å. Later, the T 1 state of the trimer converts to a tetramer (tetramer state in Fig. 1) on nanosecond time scale. Finally, the Au ions returned to their original loosely interacting bent structure.
In this research, the direct observation of a very fast chemical reaction, induced by the photo-excitation, was succeeded (Fig. 2, 3). Therefore, this method is expected to be a fundamental technology for understanding the light energy conversion reaction. The research group is actively working to apply this method to the development of viable renewable energy resources, such as a photocatalysts for artificial photosynthesis using sunlight.
This research was supported by the X-ray Free Electron Laser Priority Strategy Program of the MEXT, PRESTO of the JST, and the the Innovative Areas "Artificial Photosynthesis (AnApple)" grant from the Japan Society for the Promotion of Science (JSPS).
Publication: Nature , 518 (19 February 2015)
Title: Direct observation of bond formation in solution with femtosecond X-ray scattering
Authors: K. H. Kim 1 , J. G. Kim 1 , S. Nozawa 1 , T. Sato 1 , K. Y. Oang, T. W. Kim, H. Ki, J. Jo, S. Park, C. Song, T. Sato, K. Ogawa, T. Togashi, K. Tono, M. Yabashi, T. Ishikawa, J. Kim, R. Ryoo, J. Kim, H. Ihee, S. Adachi. ※ 1: These authors contributed equally to the work.
DOI: 10.1038/nature14163
Figure 1. Structure of a gold cyano trimer complex (Au(CN) 2 - ) 3 .
Figure 2. Observed changes in the molecular structure of the gold complex
Figure 3. Schematic view of the research of photo-chemical reactions by the molecular movie
2015.02.27 View 12470 -
KAIST Develops Subminiature, Power-Efficient Air Pollution Sensing Probe
Professor Inkyu Park and his research team from the Department of Mechanical Engineering at KAIST have developed a subminiature, power-efficient air-pollution sensing probe that can be applied to mobile devices. Their research findings were published online in the January 30th issue of Scientific Reports.
As air pollution has increased, people have taken greater interest in health care. The developed technology could allow people to measure independently the air pollution level of their surrounding environments.
Previous instruments used to measure air pollution levels were bulky and consumed a lot of power. They also often produced inaccurate results when measuring air pollution in which different toxic gases were mixed. These problems could not be resolved with existing semiconductor manufacturing process.
Using local temperature field control technology, Professor Park’s team succeeded in integrating multiple heterogeneous nanomaterials and fitting them onto a small, low-power electronic chip. This microheating sensor can heat microscale regions through local hydrothermal synthesis. Because it requires a miniscale amount of nanomaterials to manufacture, the sensor is most suitable for mobile devices.
Professor Park said, “Our research will contribute to the development of convergence technology in such field as air pollution sensing probes, biosensors, electronic devices, and displays.”
The team's research was supported by the Ministry of Education and the Ministry of Science, ICT and Future Planning, Republic of Korea.
Figure 1 – The Concept of Multiple Nanomaterial Device and Numerical Simulation Results of Precursor Solutions
Figure 2 - Multiple Nanomaterial Manufactured in a Microscale Region
2015.02.27 View 10719 -
KAIST Team Wins International Hacking Competition, "SECCON CTF 2014"
KAIST’s white hacker team, “TOFEL Beginner,” secured the first place in an international hacking competition, SECCON CTF 2014. SECCON is an international hacking competition which has operated for more than 20 years. It uses the Capture the Flag (CTF) method. Last year’s competition was held in Tokyo on December 7, 2014.
The TOFEL Beginner team consisted of two KAIST graduate students and two researchers from a private security company based in Korea: In-Soo Yoon of Computer Science, Eun-Soo Kim of the Graduate School of Information Security (GSIS), and Jong-Ho Lee and Jung-Hoon Lee of Raon Secure.
Of 4,186 competitors, 24 teams made it to the finals. The TOFEL Beginner took the lead with 4,506 points compared with HITCON (3,112 points) of Taiwan and PPP (2,858 points) of the USA.
With this victory, the KAIST team qualified to participate in the most renowned international hacking competition, the DEF CON Hacking Conference in 2015.
Professor Yongdae Kim of the Electrical Engineering Department at KAIST, who advised the TOEFL Beginner team, said, “Our members have achieved an outstanding result. By taking advantage of this opportunity, KAIST will continue to offer the best programs in information security in Korea and hopefully beyond.”
2015.02.24 View 10097 -
President Kang to Present at the World Economic Forum
President Sung-Mo Kang of KAIST will attend the World Economic Forum (WEF) as a member of the Global University Leaders Forum (GULF) to represent KAIST. GULF is attended by the world leaders of education and research. Its members represent 26 universities drawn from around the world including Harvard University. KAIST is the only Korean university to be invited.
WEF will be held in Davos, Switzerland, for four days, starting on 21 January 2015. He will discuss the future of higher education, the issues and solutions of science and society at GULF.
By attending GULF, KAIST expects to strengthen its network with top universities around the world and raise KAIST’s profile on an international basis. President Kang said, “The invitation for KAIST to attend the GULF is an evidence of its raised global status.” He continued, “I will show the innovative and challenging achievements KAIST has made to the leaders of the world.”
The theme of the 2015 World Economic Forum Annual Meeting 2015 is “The New Global Context” to discuss the integration of economic growth and society, employment and work force, environment and resource scarcity, the future of the Internet, and international crime and anti-corruption.
The World Economic Forum was established in 1971 by Klaus Schwab who is also its Executive Chairman. More than 2,500 people including German Chancellor Angela Merkel, French President François Hollande, Chinese Premier Li Keqiang, Google President Eric Schmidt, and Microsoft CEO Satya Nadella will attend this year's forum.
2015.01.22 View 8727 -
President Steve Kang will serve as the Chairman of Global Agenda Council on the Future of Electronics of the World Economic Forum
President Steve Kang of KAIST has been appointed to the Chairman of the Global Agenda Council (GAC) on the Future of Electronics of the World Economic Forum (WEF). He will serve the position for two years until September 2016.
President Kang and WEF council members co-hosted, with the government of the United Arab Emirates (UAE), the Future Circles Initiative, a future-focused, innovative brainstorming conference to help find strategies and ideas for the development of UAE. The conference took place on November 11-12, 2014 at the Mina Al Salam Hotel in Dubai.
WEF has about 80 GACs. Each council consists of 15 experts and thought leaders from the academia, industry, government, business, and non-profit sector and deals with specific issues that are important and relevant to the global community such as ageing, artificial intelligence and robotics, brain research, food and nutrition security, education, social media, and future of chemicals, advanced materials and biotechnology.
President Kang was recognized for his contribution to the advancement of science and higher education as an engineer, scholar, and professor. He led the development of the world’s premier CMOS 32-bit microprocessors while working at the AT&T Bell Laboratories. He also taught and conducted research at the University of California, Santa Cruz, and the University of Illinois, Urbana-Champaign. President Kang served as the chancellor of the University of California at Merced from March 2007 to June 2011.
2014.11.11 View 9268 -
KAIST and the International Institute for Applied Systems Analysis Agree to Cooperate
KAIST signed a cooperation agreement with the International Institute for Applied Systems Analysis (IIASA) on October 29, 2014 at the president’s office.
Established in 1972 and based in Austria as a non-governmental research organization, IIASA is an international scientific institute that conducts policy-oriented research into global problems such as climate change, energy security, or population aging. IIASA examines such issues and devises strategies for cooperative action unconstrained by political and national self-interest.
Dr. Pavel Kabat, the Director General and CEO of IIASA, headed a delegation that visited KAIST to attend the signing ceremony of the agreement. He said, “KAIST has been known as a leading research university, and its strength in the development of green technology and environmental policy will benefit our institution. In particular, we expect to see vibrant exchanges of knowledge and researchers with the Graduate School of Green Growth (GSGG) and the Graduate School of EEWS (energy, environment, water, and sustainability) at KAIST.”
The two organizations will implement joint research projects in the diffusion analysis of green technology, the development and improvement of evaluation models to integrate economy, energy, and environment, the development of an analysis system for water resources, and the establishment of academic workshops and conferences.
The Dean of GSGG, Professor Jae-Kyu Lee said, “IIASA is a well-respected international organization with accumulated knowledge about analysis and prediction techniques. With this agreement, we hope that KAIST will intensify its research capacity in environmental science and lead education and research in green growth and environmental technology.”
The picture below shows Dr. Pavel Kabat, the Director General and CEO of IIASA, on the left and President Steve Kang of KAIST on the right holding the signed agreement with professors from GSGG and EEWS Graduate School including Professor Jae-Kyu Lee, to the right of President Kang.
2014.11.05 View 10614 -
KAIST and Petersburg State Transport University Sign a MOU on Green Transportation
The Petersburg State Transport University (PSTU) in Russia is a higher education institution specializing in railway transport.
KAIST and PSTU signed a memorandum of understating (MOU) on October 28, 2014 at the KAIST campus and agreed to collaborate in the research of and hold academic exchanges for green transportation.
Based on the agreement, the two institutions will collaborate in the development of a high capacity railway that is powered through wireless power transfer technology and will exchange personnel and academic knowledge to advance the field of green transportation.
The Graduate School for Green Transportation (GSGT) at KAIST organized a seminar which took place after the MOU signing ceremony. Professor Dong-Ho Cho, the Dean of GSGT, presented a keynote speech at the seminar on “Korea’s Green Transportation Policy and Its Technology Development Status” to the audience including the PSTU delegation.
Established in 1809, PSTU is one of the oldest and most prestigious engineering universities in Russia, serving as an important scientific and research center in the area of engineering, construction, and railway operation.
2014.11.04 View 9284 -
The 2014 SoC Robot Competition Took Place
Professor Hoi-Jun Yoo of the Department of Electrical Engineering at KAIST and his research team hosted a competition for miniature robots with artificial intelligence at KINTEX in Ilsan, Korea, on October 23-26, 2014.
The competition, called the 2014 SoC Robot War, showed the latest developments of semiconductor and robot technology through the robots’ presentations of the Korean martial art, Taekwondo, and hurdles race. SoC is a system on ship, an integrated circuit that holds all components of a computer or other electronic systems in a single chip. SoC robots are equipped with an artificial intelligence system, and therefore, can recognize things on their own or respond automatically to environmental changes. SoC robots are developed with the integration of semiconductor technology and robotics engineering.
Marking the thirteenth competition this year since its inception, the Robot War featured two competitions between HURO and Taekwon Robots. Under the HURO competition, participating robots were required to run a hurdle race, pass through barricades, and cross a bridge. The winning team received an award from the president of the Republic of Korea. Robots participating in the Taekwon Robot competition performed some of the main movements of Taekwondo such as front and side kicks and fist techniques. The winning team received an award from the prime minster of the Republic of Korea.
A total of 105 teams with 530 students and researchers from different universities across the country participated in preliminaries, and 30 teams qualified for the final competition.
2014.10.27 View 8681 -
Development of a Photonic Diode with Light Speed, Single-Direction Transfer
A photonic diode using a nitride semiconductor rod can increase the possibility of developing all-optical integrated circuits, an alternative to conventional integrated circuits.
Professor Yong-Hoon Cho's research team from the Department of Physics, KAIST, developed a photonic diode which can selectively transfer light in one way, using semiconductor rods.
The photonic diode has a diameter of hundreds of nanometers (nm) and a length of few micrometers. This size enables its use in large-scale integration (LSI). The diode’s less sensitivity towards polarized light angle makes it more useful.
In an integrated circuit, a diode controls the flow of electrons. If this diode controls light rather than electrons, data can be transferred at high speed, and its loss is minimized to a greater extent. Since these implementations conserve more energy, this is a very promising future technology.
However, conventional electronic diodes, made up of asymmetric meta-materials or photonic crystalline structures, are large, which makes them difficult to be used in LSI. These diodes could only be implemented under limited conditions due to its sensitivity towards polarized light angle.
The research team used nitride semiconductor rods to develop a highly efficient photonic diode with distinct light intensities from opposite ends.
The semiconductor rod yields different amount of energy horizontally. According to the research team, this is because the width of the quantum well and its indium quantity is continuously controlled.
Professor Cho said, "A large energy difference in a horizontal direction causes asymmetrical light propagation, enabling it to be operated as a photonic diode." He added that “If light, instead of electrons, were adopted in integrated circuits, the transfer speed would be expected as great as that of light.”
The research findings were published in the September 10th issue of Nano Letters as the cover paper.
Under the guidance of Professor Cho, two Ph.D. candidates, Suk-Min Ko and Su-Hyun Gong, conducted this research. This research project was sponsored by the National Research Foundation of Korea and KAIST’s EEWS (energy, environment, water, and sustainability) Research Center.
Figure Description: Computer simulated image of photonic diode made of semiconductor rod implemented in an all-optical integrated circuit
2014.09.23 View 11419 -
PIBOT, a small humanoid robot flies an aircraft
The 2014 IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS 2014) took place in Chicago, Illinois, on September 14-18, 2014.
Professor David Hyunchul Shim and his students from the Department of Aerospace Engineering, KAIST, presented a research paper entitled “A Robot-machine Interface for Full-functionality Automation Using a Humanoid” at the conference.
The robot called “PIBOT,” a pint-sized, tiny humanoid robot, uses a mixture of flight data and visuals to fly an airplane, capable of identifying and operating all of the buttons and switches in the cockpit of a normal light aircraft designed for humans.
For now, the robot is only flying a simulator, but Professor Shim expects that “PIBOT will help us have a fully automated flight experience, eventually replacing human pilots.”
The IEEE Spectrum magazine published an article on PIBOT posted online September 18, 2014. Please follow the link below for the article:
IEEE Spectrum, September 18, 2014
Tiny Humanoid Robot Learning to Fly Real Airplanes
http://spectrum.ieee.org/automaton/robotics/humanoids/tiny-humanoid-robot-learning-to-fly-real-airplanes
2014.09.23 View 13584 -
2014 NEREC Conference on Nuclear Nonproliferation: July 31-August 1, 2014, Seoul
The Nonproliferation Education and Research Center (NEREC) at KAIST hosted an international conference on nuclear nonproliferation on July 31-August 1, 2014 in Seoul. The Ministry of Science, ICT and Future Planning, the Korean Nuclear Safety and Security Commission, and the Korea Nuclear Policy Society (KNPS) sponsored the event.
Over one hundred experts and "thought leaders" in nuclear security and nonproliferation attended the conference and discussed issues related to the nonproliferation of nuclear weapons, the role of scientific community in mitigating nuclear threat and promoting the peaceful use of nuclear power, and nuclear disarmament policy.
Keynote speakers were: Steven E. Miller, Director of International Security Program at Belfer Center for Science and International Affairs, Harvard University; Scott D. Sagan, Senior Fellow of the Center for International Security and Cooperation, Freeman Spogli Institute for International Studies, Stanford University; Mark Fitzpatrick, Director of the Nonproliferation and Disarmament Programme, International Institute for Strategic Studies; Sang-Hyun Lee, Director of Security Strategy, Sejong Institute; and Man-Sung Yim, Professor of Nuclear and Quantum Engineering, KAIST.
At the conference, Professor Yim, Director of KAIST NEREC said, “Korea has grown to become a key player in the development of commercial nuclear energy over the past decades. We hope that our conference encourages Korea to be more involved in the efforts of the international community to enhance the global nonproliferation regime.”
2014.08.05 View 14012 -
Professor Min Hyuk Kim Appointed an Associate Editor on ACM Transactions on Graphics
Professor Min Hyuk Kim of KAIST's Computer Science Department has been appointed an associate editor for a prestigious international journal in the field of graphics, ACM Transactions on Graphics (TOG).
Founded in 1947, the Association for Computing Machinery (ACM) is the world’s largest educational and scientific computing society, delivering knowledge that advances computing as a science and profession.
Published during the past 35 years, ACM TOG is a highly regarded, peer-reviewed scientific journal that aims to disseminate the latest findings of research in computer graphics. Professor Kim is the first Korean scholar to serve the journal as an editor.
Professor Kim’s responsibilities are many, and they include selecting appropriate reviewers for submitted manuscripts to be published in the journal and reporting the results of review process.
He said, “The appointment was a great honor, and I’m looking forward to having the opportunity to make further contributions to the advancement of the graphics field.”
Professor Kim has published numerous papers on computer graphics with a focus on research in 3D imaging spectroscopy and visual perception.
2014.07.14 View 10288